Intra-/Intermolecular Bifurcated Chalcogen Bonding in Crystal Structure of Thiazole/Thiadiazole Derived Binuclear (Diaminocarbene)PdII Complexes

Intra-/Intermolecular Bifurcated Chalcogen Bonding in Crystal Structure of Thiazole/Thiadiazole Derived Binuclear (Diaminocarbene)PdII Complexes

The coupling of cis-[PdCl2(CNXyl)2] (Xyl = 2,6-Me2C6H3) with 4-phenylthiazol-2-amine in molar ratio 2:3 at RT in CH2Cl2 leads to binuclear (diaminocarbene)PdII complex 3c. The complex was characterized by HRESI+-MS, 1H NMR spectroscopy, and its structure was elucidated by single-crystal XRD. Inspect...

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Bibliographic Details
Main Authors: Alexander S. Mikherdov, Alexander S. Novikov, Mikhail A. Kinzhalov, Andrey A. Zolotarev, Vadim P. Boyarskiy
Format: Article
Language:English
Published: MDPI AG 2018-02-01
Series:Crystals
Subjects:
Chalcogen bonding
non-covalent interactions
Hirshfeld surface analysis
AIM analysis
diaminocarbene complexes
Online Access:http://www.mdpi.com/2073-4352/8/3/112

Internet

http://www.mdpi.com/2073-4352/8/3/112

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