Reduction of Bromo- and Iodo-2,6-bis(diphenylphosphanylmethyl)benzene with Magnesium and Calcium

Reduction of Bromo- and Iodo-2,6-bis(diphenylphosphanylmethyl)benzene with Magnesium and Calcium

Arylmagnesium and -calcium reagents are easily accessible; however, ether degradation processes limit storability, especially of the calcium-based heavy Grignard reagents. Ortho-bound substituents with phosphanyl donor sites usually block available coordination sites and stabilize such complexes. Th...

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Bibliographic Details
Main Authors: Alexander Koch, Sven Krieck, Helmar Görls, Matthias Westerhausen
Format: Article
Language:English
Published: MDPI AG 2016-12-01
Series:Inorganics
Subjects:
Grignard reagent
arylmagnesium halide
phosphinates
calcium phosphinates
direct synthesis
ether degradation
calcium bromide
Online Access:http://www.mdpi.com/2304-6740/4/4/39

Internet

http://www.mdpi.com/2304-6740/4/4/39

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