Solvent tuning of photochemistry upon excited-state symmetry breaking

Symmetric multibranched donor-acceptor molecules are promising photoactive materials for diverse applications. Here the authors show that, in octupolar and quadrupolar dyes, excited-state symmetry breaking occurs efficiently in polar solvents only and results in a concentration of the excitation tha...

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Bibliographic Details
Main Authors: Bogdan Dereka, Denis Svechkarev, Arnulf Rosspeintner, Alexander Aster, Markus Lunzer, Robert Liska, Aaron M. Mohs, Eric Vauthey
Format: Article
Language:English
Published: Nature Publishing Group 2020-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-15681-3