Solid State and Solution Study on the Formation of Inorganic Anion Complexes with a Series of Tetrazine-Based Ligands

Solid State and Solution Study on the Formation of Inorganic Anion Complexes with a Series of Tetrazine-Based Ligands

Four molecules (L1−L4) constituted by an s-tetrazine ring appended with two identical aliphatic chains of increasing length bearing terminal morpholine groups were studied as anion receptors in water. The basicity properties of these molecules were also investigated. Speciation of the anio...

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Bibliographic Details
Main Authors: Matteo Savastano, Celeste García-Gallarín, Claudia Giorgi, Paola Gratteri, Maria Dolores López de la Torre, Carla Bazzicalupi, Antonio Bianchi, Manuel Melguizo
Format: Article
Language:English
Published: MDPI AG 2019-06-01
Series:Molecules
Subjects:
<i>s</i>-tetrazines
anion complexes
anion–π interactions
lone pair–π interactions
H bonding
supramolecular forces
crystal structures
stability constants
complexation enthalpy
Online Access:https://www.mdpi.com/1420-3049/24/12/2247

Internet

https://www.mdpi.com/1420-3049/24/12/2247

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