Negative and positive thermal expansion-like volume changes due to intermetallic charge transfer based on an ionic crystal model of transition-metal oxides
Materials showing negative thermal expansion (NTE) are technologically important and a few transition-metal oxides with the perovskite structure show large NTE-like volume changes due to intermetallic charge transfer. Here we show that the observed volume changes are primarily caused by the size eff...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
AIP Publishing LLC
2018-08-01
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| Series: | APL Materials |
| Online Access: | http://dx.doi.org/10.1063/1.5042510 |