The synthesis and crystal structure of bis[3,3-diethyl-1-(phenylimino-κN)thiourea-κS]silver hexafluoridophosphate

The synthesis and crystal structure of bis[3,3-diethyl-1-(phenylimino-κN)thiourea-κS]silver hexafluoridophosphate

The structure of the title complex, [Ag(C11H15N3S)2]PF6, has monoclinic (P21/c) symmetry, and the silver atom has a distorted square-planar geometry. The coordination complex crystallized from mixing silver hexafluoridophosphate with a concentrated tetrahydrofuran solution of N,N-diethylphenylazothi...

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Bibliographic Details
Main Authors: Vincent M. Groner, Garrett E. Larson, Yuwei Kan, Mark F. Roll, James G. Moberly, Kristopher V. Waynant
Format: Article
Language:English
Published: International Union of Crystallography 2019-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
arylazothioformamide
silver
distorted square planar
square-pyramidal
polymeric chain
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019011824

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http://scripts.iucr.org/cgi-bin/paper?S2056989019011824

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