Controlling Thermal Expansion Behaviors of Fence-Like Metal-Organic Frameworks by Varying/Mixing Metal Ions
Solvothermal reactions of 3-(4-pyridyl)-benzoic acid (Hpba) with a series of transition metal ions yielded isostructral metal-organic frameworks [M(pba)2]·2DMA (MCF-52; M = Ni2+, Co2+, Zn2+, Cd2+, or mixed Zn2+/Cd2+; DMA = N,N-dimethylacetamide) possessing two-dimensional fence-like coordination net...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Frontiers Media S.A.
2018-07-01
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Series: | Frontiers in Chemistry |
Subjects: | |
Online Access: | https://www.frontiersin.org/article/10.3389/fchem.2018.00306/full |