STABILIZATION OF UNUSUAL SUBSTRATE COORDINATION MODES IN DINUCLEAR MACROCYCLIC COMPLEXES
The steric protection offered by the macrobinucleating hexaazaditiophenolate ligand (L) allows for the preparation of the first stable dinuclear nickel(II) borohydride bridged complex, which reacts rapidly with elemental sulphur producing a tetranuclear nickel(II) complex [{(L)Ni2}2(μ-S6)]2+ bear...
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Format: | Article |
Language: | English |
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Academy of Sciences of Moldova, Institute of Chemistry
2010-06-01
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Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
Subjects: | |
Online Access: | http://www.cjm.asm.md/sites/default/files/article_files/24-35%20Lozan.pdf |