STABILIZATION OF UNUSUAL SUBSTRATE COORDINATION MODES IN DINUCLEAR MACROCYCLIC COMPLEXES

The steric protection offered by the macrobinucleating hexaazaditiophenolate ligand (L) allows for the preparation of the first stable dinuclear nickel(II) borohydride bridged complex, which reacts rapidly with elemental sulphur producing a tetranuclear nickel(II) complex [{(L)Ni2}2(μ-S6)]2+ bear...

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Bibliographic Details
Main Author: Vasile Lozan
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2010-06-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/24-35%20Lozan.pdf