An Improved Model for the Steric-Entropic Effect on the Retention of Rod-like Particles in Field-Flow Fractionation: Discussion of Aspect Ratio-Based Separation
We developed an improved model for predicting the steric-entropic effect on the separation behaviors of rod-like particles in flow field-flow fractionation. Our new model incorporates the “pole-vault” rotation of a rod-like particle near a wall under shear flow into the original model developed by B...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2015-07-01
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Series: | Chromatography |
Subjects: | |
Online Access: | http://www.mdpi.com/2227-9075/2/3/472 |