Two New Three-Dimensional Pillared-Layer Co(II) and Cu(II) Frameworks Involving a [M2(EO-N3)2] Motif from a Semi-Flexible N-Donor Ligand, 5,5′-Bipyrimidin: Syntheses, Structures and Magnetic Properties

Two New Three-Dimensional Pillared-Layer Co(II) and Cu(II) Frameworks Involving a [M2(EO-N3)2] Motif from a Semi-Flexible N-Donor Ligand, 5,5′-Bipyrimidin: Syntheses, Structures and Magnetic Properties

Two new three-dimensional (3D) Co(II)- and Cu(II)-azido frameworks, [Co2(N3)4(bpym)2]n (1) and [Cu2(N3)4(bpym)]n (2), were successfully synthesized by introducing a semi-flexible N-donor ligand, 5,5′-bipyrimidin (bpym), with different bridging modes and orientations. Compounds 1 and 2 were structura...

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Bibliographic Details
Main Authors: Zu-Zhen Zhang, Han-Ting Chang, Yi Lin Kuo, Gene-Hsiang Lee, Chen-I Yang
Format: Article
Language:English
Published: MDPI AG 2018-02-01
Series:Polymers
Subjects:
semi-flexible N-donor ligand
coordination polymer
magnetic properties
spin canting
metamagnetism
spin-flop
Online Access:http://www.mdpi.com/2073-4360/10/3/229

Internet

http://www.mdpi.com/2073-4360/10/3/229

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