Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate

The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexanuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intramolecular N—H...N hydrogen bond and the c...

Full description

Bibliographic Details
Main Authors:	Chun-Wei Yeh, Chia-Her Lin, Jhy-Der Chen
Format:	Article
Language:	English
Published:	International Union of Crystallography 2008-01-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536807062897

id	doaj-66bd2c5bf076467784247ce2ebda0114
record_format	Article
spelling	doaj-66bd2c5bf076467784247ce2ebda01142020-11-25T00:17:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m41m4110.1107/S1600536807062897Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdateChun-Wei YehChia-Her LinJhy-Der ChenThe title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexanuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intramolecular N—H...N hydrogen bond and the cations are linked through self-complementary pairs of N—H...N hydrogen bonds into dimers across centres of inversion. The cations and anions are interlinked through C—H...O contacts.http://scripts.iucr.org/cgi-bin/paper?S1600536807062897
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Chun-Wei Yeh Chia-Her Lin Jhy-Der Chen
spellingShingle	Chun-Wei Yeh Chia-Her Lin Jhy-Der Chen Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate Acta Crystallographica Section E
author_facet	Chun-Wei Yeh Chia-Her Lin Jhy-Der Chen
author_sort	Chun-Wei Yeh
title	Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate
title_short	Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate
title_full	Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate
title_fullStr	Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate
title_full_unstemmed	Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate
title_sort	bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate
publisher	International Union of Crystallography
series	Acta Crystallographica Section E
issn	1600-5368
publishDate	2008-01-01
description	The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexanuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intramolecular N—H...N hydrogen bond and the cations are linked through self-complementary pairs of N—H...N hydrogen bonds into dimers across centres of inversion. The cations and anions are interlinked through C—H...O contacts.
url	http://scripts.iucr.org/cgi-bin/paper?S1600536807062897
work_keys_str_mv	AT chunweiyeh bis2pyrimidin2ylaminopyrimidiniumhexamolybdate AT chiaherlin bis2pyrimidin2ylaminopyrimidiniumhexamolybdate AT jhyderchen bis2pyrimidin2ylaminopyrimidiniumhexamolybdate
_version_	1725378992809181184

Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate

Similar Items