Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate

The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexanuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intramolecular N—H...N hydrogen bond and the c...

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Bibliographic Details
Main Authors: Chun-Wei Yeh, Chia-Her Lin, Jhy-Der Chen
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807062897