Photochemical and Beckmann rearrangement of (Z)-cholest-4-en-6-one oxime

Photochemical and Beckmann rearrangement of (Z)-cholest-4-en-6-one oxime

Beckmann rearrangement of (Z)-cholest-4-en-6-one oxime (4) (prepared in 4 steps starting from cholest-5-en-3β-ol ο1)) with thionyl chloride in dioxane solution afforded an enamide-type lactam, i.e. 7-aza-B-homocholest-4-en-6-one (6) as a single product. Photoreaction of the same compound in methanol...

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Bibliographic Details
Main Authors: Krstić Natalija M., Bjelaković Mira S., Dabović Milan M., Lorenc Ljubinka B., Pavlović Vladimir D.
Format: Article
Language:English
Published: Serbian Chemical Society 2004-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
(z)-cholest-4-en-6-one oxime
7-aza-b-homocholest-4-en-6-one
beckmann rearrangement
photoreaction
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390406413K.pdf

Internet

http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390406413K.pdf

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