mechanistic investigation of the oxidation of N,a-diphenylnitrones by dichloramine-T in aqueous acetonitrile medium – a non-linear Hammett plot

mechanistic investigation of the oxidation of N,a-diphenylnitrones by dichloramine-T in aqueous acetonitrile medium – a non-linear Hammett plot

The kinetics of oxidation of a number of meta- and para-substituted N,a-diphenylnitrones (nitrone) by dichloramine-T (DCT) was investigated in the presence of alkali in aqueous acetonitrile medium. The order with respect to DCT was one and to OH- an inverse fractional order. The reaction was first o...

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Bibliographic Details
Main Authors: SUBRAMANIAN MANIVARMAN, GOVINDASAMY RAJARAJAN, GOVINDASAMY MANIKANDAN, MAHALIGAM SEKAR, JAYARAMAN JAYABHARATHI, VENUGOPAL THANIKACHALAM
Format: Article
Language:English
Published: Serbian Chemical Society 2009-05-01
Series:Journal of the Serbian Chemical Society
Subjects:
nitrones
kinetics
dichloramine-T
non-linear concave downward curve
Online Access:http://www.shd.org.rs/JSCS/Vol74/No5/02_3905_3849.pdf

Internet

http://www.shd.org.rs/JSCS/Vol74/No5/02_3905_3849.pdf

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