Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst

Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst

The direct substitution of the OH group of stereogenic alcohols are reported rarely in literature. Here, the authors demonstrate direct substitution of both secondary and tertiary alcohols with chirality transfer leading to enantioenriched 5-membered, 6-membered and aryl-fused 6-membered heterocycli...

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Bibliographic Details
Main Authors: Rahul A. Watile, Anon Bunrit, Jèssica Margalef, Sunisa Akkarasamiyo, Rabia Ayub, Emi Lagerspets, Srijit Biswas, Timo Repo, Joseph S. M. Samec
Format: Article
Language:English
Published: Nature Publishing Group 2019-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-11838-x

Internet

https://doi.org/10.1038/s41467-019-11838-x

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