Unexpected reactivity of “GaI” towards N,N′-diaryl-β-diketiminate tin(II) chloride: Synthesis, X-ray diffraction analysis and DFT studies

Unexpected reactivity of “GaI” towards N,N′-diaryl-β-diketiminate tin(II) chloride: Synthesis, X-ray diffraction analysis and DFT studies

Reaction of the [HC(CMeNAr)2]SnCl (Ar = 2,4,6-Me3C6H2) with “GaI” in THF provided an unexpected transhalogenation reaction product [HC(CMeNAr)2]SnI. The crystal structure shows a tin(II) ion with a distorted tetrahedral pyramidal geometry. Theoretical calculations, using density functional theory (B...

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Bibliographic Details
Main Authors: Marisol Ibarra-Rodríguez, Víctor M. Jiménez-Pérez, Blanca M. Muñoz-Flores, Noemi Waksman, Rosalba Ramírez, Mario Sánchez, Iran F. Hernández-Ahuactzi
Format: Article
Language:English
Published: Elsevier 2019-12-01
Series:Arabian Journal of Chemistry
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535215002701

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http://www.sciencedirect.com/science/article/pii/S1878535215002701

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