Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes

Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes

Novel multistage redox tetrathiafulvalenes (TTFs) bearing 6-aryl-1,4-dithiafulvene moieties were synthesized by palladium-catalyzed direct C–H arylation. In the presence of a catalytic amount of Pd(OAc)2, P(t-Bu3)·HBF4, and an excess of Cs2CO3, the C–H arylation of TTF with several aryl bromides bea...

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Bibliographic Details
Main Authors: Aya Yoshimura, Hitoshi Kimura, Kohei Kagawa, Mayuka Yoshioka, Toshiki Itou, Dhananjayan Vasu, Takashi Shirahata, Hideki Yorimitsu, Yohji Misaki
Format: Article
Language:English
Published: Beilstein-Institut 2020-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
cross-conjugated systems
electrochemical properties
extended π-conjugation
digital simulation analysis
tetrathiafulvalene
Online Access:https://doi.org/10.3762/bjoc.16.86

Internet

https://doi.org/10.3762/bjoc.16.86

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