Design, Synthesis, Characterization of Novel Ruthenium(II) Catalysts: Highly Efficient and Selective Hydrogenation of Cinnamaldehyde to (E)-3-Phenylprop-2-en-1-ol

Design, Synthesis, Characterization of Novel Ruthenium(II) Catalysts: Highly Efficient and Selective Hydrogenation of Cinnamaldehyde to (E)-3-Phenylprop-2-en-1-ol

In this contribution, two novel supported and non-supported ruthenium(II) complexes of type [RuCl2(dppme)(NN)] where [dppme is H2C=C(CH2PPh2)2 and NN is N1-(3-(trimethoxysilyl)propyl)ethane-1,2-diamine] were prepared. The NN co-ligand caused release of one of the dppme ligands from [RuCl2(dppme)2] p...

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Bibliographic Details
Main Authors: Hany W. Darwish, Assem Barakat, Ayman Nafady, Mohammed Suleiman, Mousa Al-Noaimi, Belkheir Hammouti, Smaail Radi, Taibi Ben Hadda, Ahmad Abu-Obaid, Mohammad S. Mubarak, Ismail Warad
Format: Article
Language:English
Published: MDPI AG 2014-05-01
Series:Molecules
Subjects:
Ru(II) complexes
hydrogenation
diphosphine
cinnamic aldehyde
NMR
Online Access:http://www.mdpi.com/1420-3049/19/5/5965

Internet

http://www.mdpi.com/1420-3049/19/5/5965

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