Tris[N,N-bis(3,5-di-tert-butylbenzyl)dithiocarbamato-κ2S,S′]-μ3-sulfido-tris-μ2-disulfido-triangulo-trimolybdenum(IV) iodide

Tris[N,N-bis(3,5-di-tert-butylbenzyl)dithiocarbamato-κ2S,S′]-μ3-sulfido-tris-μ2-disulfido-triangulo-trimolybdenum(IV) iodide

The title compound, [Mo3(C31H46NS2)3S7]I, crystallizes on a threefold rotational axis in P31c (space group No. 159). The [Mo3S7(S2CN(CH2C6H3-3,5-tBu2)2)3]+ cations are arrayed in sheets in the ab plane with interligand hydrophobic interactions between tert-butyl groups guiding the packing arrangemen...

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Bibliographic Details
Main Authors: Yueli Chen, Bo Wang, Patricia Fontenot, James P. Donahue
Format: Article
Language:English
Published: International Union of Crystallography 2020-07-01
Series:IUCrData
Subjects:
crystal structure
molybdenum-sulfide cluster
bulky dithiocarbamate anion
dispersion forces
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314620009396

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314620009396

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