4-Pyridylnitrene and 2-pyrazinylcarbene

4-Pyridylnitrene and 2-pyrazinylcarbene

Both flash vacuum thermolysis (FVT) and matrix photolysis generate 2-diazomethylpyrazine (22) from 1,2,3-triazolo[1,5-a]pyrazine (24). FVT of 4-azidopyridine (18) as well as of 24 or 2-(5-tetrazolyl)pyrazine (23) affords the products expected from the nitrene, i.e., 4,4’-azopyridine and 2- and 3-cya...

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Bibliographic Details
Main Authors: Curt Wentrup, Ales Reisinger, David Kvaskoff
Format: Article
Language:English
Published: Beilstein-Institut 2013-04-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
carbene–nitrene interconversion
diazepines
flash vacuum thermolysis
matrix photochemistry
nitrile ylides
reactive intermediates
Online Access:https://doi.org/10.3762/bjoc.9.85

Internet

https://doi.org/10.3762/bjoc.9.85

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