Kinetics and Mechanism of the Substitution of Ligand (Urea) of [Ti(ur)6]3+ by H2O and SCN¯ in Ethanol Solution
The kinetics of substitution of [Ti(ur)6]3+ by H2O and SCN¯ ion in ethanol solution have been measured spectrophotometrically by stopped-flow method. Water is a good nucleophile toward Ti(III) substrates. Even the solvent ethanol appears to be a poor ligand when compared to water. Substitution, in g...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1987-06-01
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Series: | Iranian Journal of Chemistry & Chemical Engineering |
Subjects: | |
Online Access: | http://www.ijcce.ac.ir/article_12271_e97b4991f6834000312f23de43cf1970.pdf |