Kinetics and Mechanism of the Substitution of Ligand (Urea) of [Ti(ur)6]3+ by H2O and SCN¯ in Ethanol Solution

The kinetics of substitution of [Ti(ur)6]3+ by H2O and SCN¯ ion in ethanol solution have been measured spectrophotometrically by stopped-flow method. Water is a good nucleophile toward Ti(III) substrates. Even the solvent ethanol appears to be a poor ligand when compared to water. Substitution, in g...

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Bibliographic Details
Main Authors: A. Kamkar, J.P. Day
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 1987-06-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_12271_e97b4991f6834000312f23de43cf1970.pdf