Theoretical Analysis of the Heterocyclic [4+2] Cycloaddition Between Pyridinium Ion and Enol Ether

Theoretical Analysis of the Heterocyclic [4+2] Cycloaddition Between Pyridinium Ion and Enol Ether

Abstract Dearomative heterocyclic [4+2] cycloaddition between the N‐(2,4‐dinitrophenyl)pyridinium ion of nicotinamide and an enol ether was analyzed by Density Functional Theory (DFT) calculations. The calculation revealed that the reaction undergoes stepwise bond formation rather than occurring in...

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Bibliographic Details
Main Authors: Masataka Nakahara, Prof. Kengo Hanaya, Prof. Takeshi Sugai, Prof. Shuhei Higashibayashi
Format: Article
Language:English
Published: Wiley-VCH 2021-06-01
Series:ChemistryOpen
Subjects:
[4+2] cycloaddition
density functional theory
pyridinium
reaction mechanism
stepwise
Online Access:https://doi.org/10.1002/open.202000310

Internet

https://doi.org/10.1002/open.202000310

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