Synthesis and crystal structure of a chloro-bridged dinuclear cadmium(II) complex with 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane
The macrocyclic ligand 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L) reacts with cadmium(II) chloride and excess NaClO4 to give a chloro-bridged dinuclear cadmium(II) complex [Cd(L)(μ-Cl)]2·2ClO4 (1). Each cadmium(II) ion exhibits a distorted octahedral environment with two chlorid...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2011-09-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc.2011.005 |