Bis(Diphenylphosphino)Methane Dioxide Complexes of Lanthanide Trichlorides: Synthesis, Structures and Spectroscopy

Bis(diphenylphosphino)methane dioxide (dppmO<sub>2</sub>) forms eight-coordinate cations [M(dppmO<sub>2</sub>)<sub>4</sub>]Cl<sub>3</sub> (M = La, Ce, Pr, Nd, Sm, Eu, Gd) on reaction in a 4:1 molar ratio with the appropriate LnCl<sub>3</sub>...

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Bibliographic Details
Main Authors: Robert D. Bannister, William Levason, Gillian Reid
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Chemistry
Subjects:
Online Access:https://www.mdpi.com/2624-8549/2/4/60