Copper-catalyzed aerobic radical C–C bond cleavage of N–H ketimines

Copper-catalyzed aerobic radical C–C bond cleavage of N–H ketimines

We report herein studies on copper-catalyzed aerobic radical C–C bond cleavage of N–H ketimines. Treatment of N–H ketimines having an α-sp3 hybridized carbon under Cu-catalyzed aerobic reaction conditions resulted in a radical fragmentation with C–C bond cleavage to give the corresponding carbonitri...

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Bibliographic Details
Main Authors: Ya Lin Tnay, Gim Yean Ang, Shunsuke Chiba
Format: Article
Language:English
Published: Beilstein-Institut 2015-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
C–C bond cleavage
copper
ketimines
molecular oxygen
radical
Online Access:https://doi.org/10.3762/bjoc.11.209

Internet

https://doi.org/10.3762/bjoc.11.209

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