Elucidating Charge Delocalization in the High-Spin State of aqueous FeII Spin-Crossover Compounds via Time-Resolved Spectroscopy in the X-ray Water Window

Elucidating Charge Delocalization in the High-Spin State of aqueous FeII Spin-Crossover Compounds via Time-Resolved Spectroscopy in the X-ray Water Window

We report the first time-resolved spectroscopy of aqueous solution in the Xray water window. Nitrogen K-edge spectra, combined with ab initio calculations, reveal distinct charge delocalization, shedding light on the origins of ultrafast spin crossover.

Bibliographic Details
Main Authors: Schoenlein Robert W., Khalil Munira, Kim Tae Kyu, Cho Hana, Strader Matthew L., Huse Nils, Van Kuiken Benjamin E.
Format: Article
Language:English
Published: EDP Sciences 2013-03-01
Series:EPJ Web of Conferences
Online Access:http://dx.doi.org/10.1051/epjconf/20134105037

Internet

http://dx.doi.org/10.1051/epjconf/20134105037

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