(2,2′-Bipyridine)chlorido[diethyl (2,2′:6′,2′′-terpyridin-4-yl)phosphonate]ruthenium(II) hexafluoridophosphate acetonitrile/water solvate

The cationic complex in the title compound, [RuCl(C10H8N2)(C19H20N3O3P)]PF6·0.83CH3CN·0.17H2O, is a water-oxidation precatalyst functionalized for TiO2 attachment via terpyridine phosphonate. The The RuII atom in the complex has a distorted octahedral geometry due to the restricted...

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Bibliographic Details
Main Authors: Weizhong Chen, Francisca N. Rein, Brian L. Scott, Reginaldo C. Rocha
Format: Article
Language:English
Published: International Union of Crystallography 2013-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813022940