Synthesis of Vinyl Chloride Monomer over Carbon-Supported Tris-(Triphenylphosphine) Ruthenium Dichloride Catalysts

Synthesis of Vinyl Chloride Monomer over Carbon-Supported Tris-(Triphenylphosphine) Ruthenium Dichloride Catalysts

A series of catalysts, including Ru/AC, Ф-P-Ru/AC, Ф-P-Ru/AC-HCl, and Ф-P-Ru/AC-HNO3, were prepared and evaluated for the hydrochlorination reaction of acetylene. The test results reveal that the Ф-P-Ru/AC-HNO3 catalyst shows superior catalytic performance with an initial acetylene conversion of 97....

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Bibliographic Details
Main Authors: Xing Li, Haiyang Zhang, Baochang Man, Chuanming Zhang, Hui Dai, Bin Dai, Jinli Zhang
Format: Article
Language:English
Published: MDPI AG 2018-07-01
Series:Catalysts
Subjects:
tris-(triphenylphosphine) ruthenium dichloride
acetylene hydrochlorination
mercury-free catalysts
enhanced interaction
Online Access:http://www.mdpi.com/2073-4344/8/7/276

Internet

http://www.mdpi.com/2073-4344/8/7/276

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