Relative substituent orientation in the structure of cis-3-chloro-1,3-dimethyl-N-(4-nitrophenyl)-2-oxocyclopentane-1-carboxamide

Relative substituent orientation in the structure of cis-3-chloro-1,3-dimethyl-N-(4-nitrophenyl)-2-oxocyclopentane-1-carboxamide

The structure of the title compound, C14H15ClN2O4, prepared by reaction of a methacryloyl dimer with nitroaniline, was determined to establish the relative substituent orientation on the cyclopentanone ring. In agreement with an earlier proposed reaction mechanism, the amide group and the methyl gro...

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Bibliographic Details
Main Authors: Matthias Zeller, Jonas Warneke, Vladimir Azov
Format: Article
Language:English
Published: International Union of Crystallography 2014-09-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
hydrogen bonds
π–π stacking
methacryloyl chloride dimer
Diels–Alder reaction
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814017711

Internet

http://scripts.iucr.org/cgi-bin/paper?S1600536814017711

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