{Sn10Si(SiMe3)2[Si(SiMe3)3]4}2-: cluster enlargement via degradation of labile ligands
For the synthesis of metalloid cluster compounds of tin applying the disproportionation reaction of subvalent metastable Sn(I) halides, Si(SiMe3)3 proved to be the ligand with the highest synthetic potential. However, degradation of the Si(SiMe3)3 ligand can also lead to cluster enlargement where ad...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2013-12-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2013-0031 |