μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}

The title compound, [Fe4(C5H5OS)2S(CO)12], was prepared by the direct reaction of Fe3(CO)12 and 2-furylmethanethiol in tetrahydrofuran. Desulfurization took place readily to form an Fe4S3 cluster. The molecule consists of two similar [(μ-2-C4H3O—CH2S)Fe2(CO)6] moieties joi...

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Bibliographic Details
Main Authors: Cong Han, Xiao-Nan Huang, Yan-Ling Guo, Wei Liu
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810022634