Bismuth Polycations Revisited: Alternative Synthesis and Electronic Structure of Bi<sub>6</sub>Br<sub>7</sub>, and Bonding in Main-Group Polyatomic Ions from a Direct Space Perspective

Bismuth Polycations Revisited: Alternative Synthesis and Electronic Structure of Bi<sub>6</sub>Br<sub>7</sub>, and Bonding in Main-Group Polyatomic Ions from a Direct Space Perspective

A bismuth subbromide, Bi<sub>6</sub>Br<sub>7</sub>, was synthesized in the form of single crystals using the reaction between Bi and Hg<sub>2</sub>Br<sub>2</sub> in a gradient furnace. Its crystal structure was reinvestigated by low-temperature single-...

Full description

Bibliographic Details
Main Authors: Ekaterina A. Stroganova, Sergey I. Troyanov, Igor V. Morozov, Alexey N. Kuznetsov
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Crystals
Subjects:
metal-metal bonds
main-group clusters
bismuth polycations
subvalent halides
crystal structure
DFT calculations
Online Access:https://www.mdpi.com/2073-4352/10/10/940

Internet

https://www.mdpi.com/2073-4352/10/10/940

Similar Items