[μ-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12 (24),13,17,19,21-decaene-23,24-diolato-κ4N3,N6,O23,O24:κ4N14,N17,O23,O24]bis(perchlorato-κO)dimanganese(II)

In the centrosymmetric and dinuclear title complex, [Mn2(C22H22N4O2)(ClO4)2], the two Mn atoms are bridged by two phenolate O atoms of the N4O2 macrocycle with an Mn...Mn distance of 2.9228 (11) Å. The distorted square–pyramidal N2O3 coordination geometry is co...

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Bibliographic Details
Main Authors:	Yi-Zhi Li, Hong Zhou, Zhi-Quan Pan, Jing Liu
Format:	Article
Language:	English
Published:	International Union of Crystallography 2008-12-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536808035551

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http://scripts.iucr.org/cgi-bin/paper?S1600536808035551

[&#956;-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12&#8197;(24),13,17,19,21-decaene-23,24-diolato-&#954;4N3,N6,O23,O24:&#954;4N14,N17,O23,O24]bis(perchlorato-&#954;O)dimanganese(II)

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[μ-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12 (24),13,17,19,21-decaene-23,24-diolato-κ4N3,N6,O23,O24:κ4N14,N17,O23,O24]bis(perchlorato-κO)dimanganese(II)