Crystal structure of the inverse crown ether tetrakis[μ2-bis(trimethylsilyl)amido]-μ4-oxido-dicobalt(II)disodium, [Co2Na2{μ2-N(SiMe3)2}4](μ4-O)

Crystal structure of the inverse crown ether tetrakis[μ2-bis(trimethylsilyl)amido]-μ4-oxido-dicobalt(II)disodium, [Co2Na2{μ2-N(SiMe3)2}4](μ4-O)

The title compound, [Co2Na2{μ2-N(SiMe3)2}4](μ4-O), (I), represents a new entry in the class of inverse crown ethers. In the molecule, each Co atom is formally in the oxidation state +II. The structure contains one half of a unique molecule per asymmetric unit with the central μ4-oxido ligand residin...

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Bibliographic Details
Main Authors: Christopher B. Hansen, Alexander S. Filatov, Gregory L. Hillhouse
Format: Article
Language:English
Published: International Union of Crystallography 2016-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
μ4-oxido ligand
cobalt
inverse crown ether
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016006861

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http://scripts.iucr.org/cgi-bin/paper?S2056989016006861

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