7-Hydroxyhexacyclo[7.5.1.01,7.06,13.08,12.010,14]pentadecan-15-one-11-spirocyclopentane

7-Hydroxyhexacyclo[7.5.1.01,7.06,13.08,12.010,14]pentadecan-15-one-11-spirocyclopentane

The reorganization of the carbon skeleton in a spiro cage dione to an unusual cage system, C19H24O2, using acid-promoted rearrangement with the aid of zinc dust as a reducing agent in the reaction medium is reported. The resulting trishomocubane hydroxyketone derivative includes five-membered rings...

Full description

Bibliographic Details
Main Authors: Sambasivarao Kotha, Subba Rao Cheekatla, Rama Gunta
Format: Article
Language:English
Published: International Union of Crystallography 2018-01-01
Series:IUCrData
Subjects:
crystal structure
propellane
cage system
ring rearrangement
ring-closing metathesis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314618000901

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314618000901

Similar Items