In Search for Titanocene Complexes with Improved Cytotoxic Activity: Synthesis, X-Ray Structure, and Spectroscopic Study of Bis(η5-cyclopentadienyl)difluorotitanium(IV)
The 1 : 2 reaction of [Ti(η5-C5H5)2Cl2] and AgF in CHCl3/H2O yielded the fluoro analog [Ti(η5-C5H5)2F2] (1) in almost quantitative yield (C5H5 is the cyclopentadienyl group). The coordination about the TiIV atom formed by two fluoro ligands and the centroids of the cyclopentadienyl rings is distorte...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Hindawi Limited
2010-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2010/914580 |