Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene

The steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)2(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electroni...

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Main Authors:	César A. Urbina-Blanco, Xavier Bantreil, Hervé Clavier, Alexandra M. Z. Slawin, Steven P. Nolan
Format:	Article
Language:	English
Published:	Beilstein-Institut 2010-11-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	N-heterocyclic carbene olefin metathesis percent buried volume ruthenium–indenylidene Tolman electronic parameter
Online Access:	https://doi.org/10.3762/bjoc.6.128

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spelling	doaj-383cbc63081d4abbb4426428feb973892021-02-02T01:53:31ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972010-11-01611120112610.3762/bjoc.6.1281860-5397-6-128Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbeneCésar A. Urbina-Blanco0Xavier Bantreil1Hervé Clavier2Alexandra M. Z. Slawin3Steven P. Nolan4EaStCHEM School of Chemistry, University of St Andrews, St Andrews KY16 9ST, United KingdomEaStCHEM School of Chemistry, University of St Andrews, St Andrews KY16 9ST, United KingdomEaStCHEM School of Chemistry, University of St Andrews, St Andrews KY16 9ST, United KingdomEaStCHEM School of Chemistry, University of St Andrews, St Andrews KY16 9ST, United KingdomEaStCHEM School of Chemistry, University of St Andrews, St Andrews KY16 9ST, United KingdomThe steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)2(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electronic) and the percent buried volume (%Vbur, steric) parameters. The corresponding ruthenium–indenylidene complexes were also synthesized and tested in benchmark metathesis transformations to establish possible correlations between reactivity and NHC electronic and steric parameters.https://doi.org/10.3762/bjoc.6.128N-heterocyclic carbeneolefin metathesispercent buried volumeruthenium–indenylideneTolman electronic parameter
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	César A. Urbina-Blanco Xavier Bantreil Hervé Clavier Alexandra M. Z. Slawin Steven P. Nolan
spellingShingle	César A. Urbina-Blanco Xavier Bantreil Hervé Clavier Alexandra M. Z. Slawin Steven P. Nolan Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene Beilstein Journal of Organic Chemistry N-heterocyclic carbene olefin metathesis percent buried volume ruthenium–indenylidene Tolman electronic parameter
author_facet	César A. Urbina-Blanco Xavier Bantreil Hervé Clavier Alexandra M. Z. Slawin Steven P. Nolan
author_sort	César A. Urbina-Blanco
title	Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene
title_short	Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene
title_full	Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene
title_fullStr	Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene
title_full_unstemmed	Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene
title_sort	backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated n-heterocyclic carbene
publisher	Beilstein-Institut
series	Beilstein Journal of Organic Chemistry
issn	1860-5397
publishDate	2010-11-01
description	The steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)2(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electronic) and the percent buried volume (%Vbur, steric) parameters. The corresponding ruthenium–indenylidene complexes were also synthesized and tested in benchmark metathesis transformations to establish possible correlations between reactivity and NHC electronic and steric parameters.
topic	N-heterocyclic carbene olefin metathesis percent buried volume ruthenium–indenylidene Tolman electronic parameter
url	https://doi.org/10.3762/bjoc.6.128
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Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene

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