Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene

Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene

The steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)2(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electroni...

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Bibliographic Details
Main Authors: César A. Urbina-Blanco, Xavier Bantreil, Hervé Clavier, Alexandra M. Z. Slawin, Steven P. Nolan
Format: Article
Language:English
Published: Beilstein-Institut 2010-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
N-heterocyclic carbene
olefin metathesis
percent buried volume
ruthenium–indenylidene
Tolman electronic parameter
Online Access:https://doi.org/10.3762/bjoc.6.128

Internet

https://doi.org/10.3762/bjoc.6.128

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