Crystal structure of (±)-(4RS,5RS,7SR)-4-[(1RS,2RS,3RS,6RS)-3-benzoyloxy-2-(2-hydroxyethyl)-6-methoxymethoxy-2-methylcyclohexyl]-8,10,10-trimethyl-2-oxo-1,3-dioxaspiro[4.5]dec-8-en-7-yl benzoate benzene monosolvate

Crystal structure of (±)-(4RS,5RS,7SR)-4-[(1RS,2RS,3RS,6RS)-3-benzoyloxy-2-(2-hydroxyethyl)-6-methoxymethoxy-2-methylcyclohexyl]-8,10,10-trimethyl-2-oxo-1,3-dioxaspiro[4.5]dec-8-en-7-yl benzoate benzene monosolvate

In the title compound, C36H44O10·C6H6, the dioxolane ring adopts an envelope conformation with the C atom bonded to the H atom as the flap, while the cyclohexene and cyclohexane rings are in half-chair and chair conformations, respectively. In the crystal, a pair of O—H...O hydrogen bonds with an R2...

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Bibliographic Details
Main Authors: Takeshi Oishi, Yuu Yamaguchi, Keisuke Fukaya, Tomoya Sugai, Ami Watanabe, Takaaki Sato, Noritaka Chida
Format: Article
Language:English
Published: International Union of Crystallography 2015-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
hydrogen bonds
taxane skeleton
paclitaxel
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989014026048

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http://scripts.iucr.org/cgi-bin/paper?S2056989014026048

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