Kinetic evaluation of the solvolysis of isobutyl chloro- and chlorothioformate esters

The specific rates of solvolysis of isobutyl chloroformate (1) are reported at 40.0 °C and those for isobutyl chlorothioformate (2) are reported at 25.0 °C, in a variety of pure and binary aqueous organic mixtures with wide ranging nucleophilicity and ionizing power. For 1, we also report the first-...

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Bibliographic Details
Main Authors: Malcolm J. D’Souza, Matthew J. McAneny, Dennis N. Kevill, Jin Burm Kyong, Song Hee Choi
Format: Article
Language:English
Published: Beilstein-Institut 2011-04-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.7.62