Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
Hydrogen borrowing is an attractive method for C-N bond formation - avoiding multiple alkylation products and reducing waste - but often is carried out with noble metals. Here the authors show that a manganese catalyst allows the selective N-alkylation of amines with alcohols.
Main Authors: | Saravanakumar Elangovan, Jacob Neumann, Jean-Baptiste Sortais, Kathrin Junge, Christophe Darcel, Matthias Beller |
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Format: | Article |
Language: | English |
Published: |
Nature Publishing Group
2016-10-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/ncomms12641 |
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