Orbital Interaction and Electron Density Transfer in PdII([9]aneB2A)L2 Complexes: Theoretical Approaches

Orbital Interaction and Electron Density Transfer in PdII([9]aneB2A)L2 Complexes: Theoretical Approaches

The geometric structures of Pd-complexes {Pd([9]aneB2A)L2 and Pd([9]aneBAB)L2 where A = P, S; B = N; L = PH3, P(CH3)3, Cl−}, their selective orbital interaction towards equatorial or axial (soft A…Pd) coordination of macrocyclic [9]aneB2A tridentate to PdL2, and electron density transfer from the el...

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Bibliographic Details
Main Authors: Jong Keun Park, Euh Duck Jeong, Mahreen Arooj, Yong-Jin Yoon, Ock Keum Kwak
Format: Article
Language:English
Published: MDPI AG 2013-10-01
Series:Molecules
Subjects:
macrocyclic tridentate
position selectivity
steric and electronic effects
orbital interaction
geometric configuration
Online Access:http://www.mdpi.com/1420-3049/18/10/12687

Internet

http://www.mdpi.com/1420-3049/18/10/12687

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