New crystal structures of alkali metal tetrakis(pentafluorophenyl)borates

The crystal structures of the salts [Li(1,2-F2C6H4)] [B(C6F5)4] (1) and Cs[B(C6F5)4] (2) comprise six Li···F contacts (1.965(3) − 2.312(3) Å) and twelve Cs···F contacts (3.0312(1) − 3.7397(2) Å), respectively, which are significantly shorter than the sum of van der Waals radii (3.29 and 4.90 Å)....

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Bibliographic Details
Main Authors: Duvinage Daniel, Schröder Artem, Lork Enno, Beckmann Jens
Format: Article
Language:English
Published: De Gruyter 2020-06-01
Series:Main Group Metal Chemistry
Subjects:
Online Access:https://doi.org/10.1515/mgmc-2020-0011