Design and synthesis of quasi-diastereomeric molecules with unchanging central, regenerating axial and switchable helical chirality via cleavage and formation of Ni(II)–O and Ni(II)–N coordination bonds

Design and synthesis of quasi-diastereomeric molecules with unchanging central, regenerating axial and switchable helical chirality via cleavage and formation of Ni(II)–O and Ni(II)–N coordination bonds

We describe herein the design and synthesis of asymmetric, pentadentate ligands, which are able to coordinate to Ni(II) cations leading to quasi-diastereomeric complexes displaying two new elements of chirality: stereogenic axis and helix along with configurational stabilization of the stereogenic c...

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Bibliographic Details
Main Authors: Vadim A. Soloshonok, José Luis Aceña, Hisanori Ueki, Jianlin Han
Format: Article
Language:English
Published: Beilstein-Institut 2012-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
axial chirality
central chirality
chiral switches
coordination bonds
functional materials
helical chirality
modular structural design
molecular devices
Online Access:https://doi.org/10.3762/bjoc.8.223

Internet

https://doi.org/10.3762/bjoc.8.223

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