Reactivity Comparison of ω-Alkenols and Higher 1-Alkenes in Copolymerization with Propylene Using An Isospecific Zirconocene-MMAO Catalyst

Reactivity Comparison of ω-Alkenols and Higher 1-Alkenes in Copolymerization with Propylene Using An Isospecific Zirconocene-MMAO Catalyst

Copolymerizations of propylene with ω-alkenols (aluminum-protected 5-hexene-1-ol (AH) and 10-undecene-1-ol (AU)) and non-polar analogues (1-hexene and 1-dodecene) were conducted with a rac-[Me2Si(2-Me-4-Ph-Ind)2]ZrCl2 activated by modified methylaluminoxane. The catalytic system showed high activity...

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Bibliographic Details
Main Authors: Benard Oloo Nyangoye, Tianyou Li, Long Chen, Zhengguo Cai
Format: Article
Language:English
Published: MDPI AG 2015-10-01
Series:Polymers
Subjects:
metallocene
propylene
ω-alkenol
copolymerization
reactivity
Online Access:http://www.mdpi.com/2073-4360/7/10/1496

Internet

http://www.mdpi.com/2073-4360/7/10/1496

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