Heteroleptic and Homoleptic Iron(III) Spin-Crossover Complexes; Effects of Ligand Substituents and Intermolecular Interactions between Co-Cation/Anion and the Complex

Heteroleptic and Homoleptic Iron(III) Spin-Crossover Complexes; Effects of Ligand Substituents and Intermolecular Interactions between Co-Cation/Anion and the Complex

The structural and magnetic properties of a range of new iron(III) bis-tridentate Schiff base complexes are described with emphasis on how intermolecular structural interactions influence spin states and spin crossover (SCO) in these d5 materials. Three pairs of complexes were investigated. The firs...

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Bibliographic Details
Main Authors: Wasinee Phonsri, Luke C. Darveniza, Stuart R. Batten, Keith S. Murray
Format: Article
Language:English
Published: MDPI AG 2017-08-01
Series:Inorganics
Subjects:
iron(III) complexes
spin crossover
heteroleptic
homoleptic
magnetism
structure
intermolecular interactions
cation–anion interactions
Online Access:https://www.mdpi.com/2304-6740/5/3/51

Internet

https://www.mdpi.com/2304-6740/5/3/51

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