Influences of Alkyl and Aryl Substituents on Iminopyridine Fe(II)- and Co(II)-Catalyzed Isoprene Polymerization

Influences of Alkyl and Aryl Substituents on Iminopyridine Fe(II)- and Co(II)-Catalyzed Isoprene Polymerization

A series of alkyl- and aryl-substituted iminopyridine Fe(II) complexes 1a–7a and Co(II) complexes 2b, 3b, 5b, and 6b were synthesized. The activator effect, influence of temperature, and, particularly, the alkyl and aryl substituents’ effect on catalytic activity, polymer molecular weight, and regio...

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Bibliographic Details
Main Authors: Lihua Guo, Xinyu Jing, Shuoyan Xiong, Wenjing Liu, Yanlan Liu, Zhe Liu, Changle Chen
Format: Article
Language:English
Published: MDPI AG 2016-11-01
Series:Polymers
Subjects:
iminopyridine
Iron(II)
Cobalt(II)
isoprene polymerization
selectivity
Online Access:http://www.mdpi.com/2073-4360/8/11/389

Internet

http://www.mdpi.com/2073-4360/8/11/389

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