Spectroscopic and Kinetic Characterization of Peroxidase-Like π-Cation Radical Pinch-Porphyrin-Iron(III) Reaction Intermediate Models of Peroxidase Enzymes

Spectroscopic and Kinetic Characterization of Peroxidase-Like π-Cation Radical Pinch-Porphyrin-Iron(III) Reaction Intermediate Models of Peroxidase Enzymes

The spectroscopic and kinetic characterization of two intermediates from the H2O2 oxidation of three dimethyl ester [(proto), (meso), (deuteroporphyrinato) (picdien)]Fe(III) complexes ([FePPPic], [FeMPPic] and [FeDPPic], respectively) pinch-porphyrin peroxidase enzyme models, with s = 5/2 and 3/2 Fe...

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Bibliographic Details
Main Authors: Samuel Hernández Anzaldo, Uriel Arroyo Abad, Armando León García, Daniel Ramírez Rosales, Rafael Zamorano Ulloa, Yasmi Reyes Ortega
Format: Article
Language:English
Published: MDPI AG 2016-06-01
Series:Molecules
Subjects:
pinch-porphyrins
peroxidases models
π-cation radical
spectroscopic studies
Online Access:http://www.mdpi.com/1420-3049/21/7/804

Internet

http://www.mdpi.com/1420-3049/21/7/804

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