Methylation-GC-MS analysis of arabinofuranose- and galactofuranose-containing structures: rapid synthesis of partially O-methylated alditol acetate standards

Methylation-GC-MS analysis of arabinofuranose- and galactofuranose-containing structures: rapid synthesis of partially O-methylated alditol acetate standards

Arabinose and galactose were treated with MeOH containing traces of H2SO4 or HCl at 25ºC to give mixtures of their methyl alpha- and beta-furanosides, as shown by 1D and 2D nuclear magnetic resonance (NMR). Oxidation of the Me alpha,beta-Araf mixture with NaIO4 preferentially oxidised the beta-isome...

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Bibliographic Details
Main Authors: Sassaki Guilherme L., Iacomini Marcello, Gorin Philip A.J.
Format: Article
Language:English
Published: Academia Brasileira de Ciências 2005-01-01
Series:Anais da Academia Brasileira de Ciências
Subjects:
partially O-methylated alditol acetates
GC-MS standards
Purdie methylation
OH reactivity
NMR
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652005000200003

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652005000200003

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