Solvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindoles

Solvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindoles

The selectivity of our previously described gold-catalyzed tandem reaction, 1,2-indole migration followed by aura-iso-Nazarov cyclization, of 3-propargylindoles bearing (hetero)aromatic substituents at both the propargylic and terminal positions, was reversed by the proper choice of the catalyst and...

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Bibliographic Details
Main Authors: Estela Álvarez, Delia Miguel, Patricia García-García, Manuel A. Fernández-Rodríguez, Félix Rodríguez, Roberto Sanz
Format: Article
Language:English
Published: Beilstein-Institut 2011-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
catalysis
gold
indoles
Nazarov cyclizations
selectivity
Online Access:https://doi.org/10.3762/bjoc.7.89

Internet

https://doi.org/10.3762/bjoc.7.89

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